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3-Chloro-2-methylpropene CAS No.563-47-3

563-47-3 - Names and IdentifiersName3-Chloro-2-methylpropeneSynonymsMACclorurodimetallileMethal

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563-47-3 - Names and Identifiers

Name3-Chloro-2-methylpropene
SynonymsMAC
clorurodimetallile
Methallyl Chloride
Cloruro di metallile
chloruredemethallyle
2-methylallyl chloride
Chlorure de methallyle
beta-Methallyl chloride
beta-methylallylchloride
3-Chloro-2-methylpropene
beta-Methylallyl chloride
3-Chloro-2-Methylpropylene
chloruedemethallyle(french)
3-chloro-2-methylprop-1-ene
chloruredemethallyle(french)
CAS563-47-3
EINECS209-251-2
InChIInChI=1/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3

563-47-3 - Physico-chemical Properties

Molecular FormulaC4H7Cl
Molar Mass90.55
Density0.925 g/mL at 20 °C (lit.)
Melting Point-80 °C (lit.)
Boling Point71-72 °C (lit.)
Flash Point9°F
Water Solubility0.5 g/L (20 ºC)
SolubilityH2O: insoluble
Vapor Presure102 mm Hg ( 20 °C)
Vapor Density3.12 (vs air)
AppearanceLiquid
ColorClear
Merck14,2148
BRN878160
Storage Condition2-8°C
Explosive Limit2.2-10.4%(V)
Refractive Indexn20/D 1.427(lit.)
Physical and Chemical Properties
  • Melting Point:<-80 ℃

  • Boiling Point: 72.2 ℃

  • flash point:-10 ℃

  • auto-ignition point: 540 ℃

  • density (g/cm3):0.9257

  • explosion limit: 3.2-8.1%

  • steam density (mg/cm3):3.12

UseFor the synthesis of acaricidal tin, sodium methallyl sulfonate, 3-chloro-2-methyl-epoxypropane

563-47-3 - Risk and Safety

Risk CodesR11 - Highly Flammable
R20/22 - Harmful by inhalation and if swallowed.
R34 - Causes burns
R43 - May cause sensitization by skin contact
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
Safety DescriptionS9 - Keep container in a well-ventilated place.
S16 - Keep away from sources of ignition.
S29 - Do not empty into drains.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
UN IDsUN 2554 3/PG 2
WGK Germany2
RTECSUC8050000
TSCAYes
HS Code29032900
Hazard Class3
Packing GroupII

563-47-3 - Reference Information

(IARC) carcinogen classification2B (Vol. 63, 115) 2018
Uses2-methyl-3-chloropropene, also known as methallyl chloride, is used to synthesize the mite agent phenobylbutylbenzene, an intermediate chlorotert-butylbenzene, It can also be used to synthesize the intermediate furan of the insecticide carbofuran.
this product is an important organic intermediate, which can be widely used in medicine, pesticide, perfume, synthetic materials and other fields. It is the main raw material for the synthesis of insecticides such as carbofuran and phenylbutyltin.
Organic intermediates are the main raw materials for the synthesis of insecticides such as carbofuran and phenylbutyltin.
Used as an intermediate for pesticides, plastics, medicines, etc.
Used to synthesize acaricidal tin, sodium methallyl sulfonate, 3-chloro-2-methylpropylene oxide, etc.
Production method2-methyl-3-chloropropene is prepared by the reaction of isobutylene and liquid chlorine. Isobutylene and liquid chlorine are measured separately after gasification, and then passed into the reactor according to the appropriate ratio. The reaction is strongly exothermic, and the reaction contact time must be strictly controlled, and the reaction is evenly mixed in an instant. After the reaction, the material enters the reaction evaporator, removes the reaction heat, and then enters the absorption condenser, absorbs hydrogen chloride into hydrochloric acid, and then is cooled and separated by oleic acid. Hydrochloric acid can be sold as a by-product, and the organic layer is fractionated to obtain 2-Methyl -3-chloropropene, the content can reach 95% ~ 98%.
categoryflammable liquid
toxicity classificationpoisoning
acute toxicityoral administration-rat LD50: 848 mg/kg; Oral administration-mouse LDL0: 3160 mg/kg
Explosive hazard characteristicsMix with air to form an explosive mixture;
flammability hazard characteristicsflammability; thermal decomposition of toxic chloride gas
storage and transportation characteristicswarehouse ventilation and low temperature drying; separate from oxidant storage and transportation
fire extinguishing agentfoam, dry powder, carbon dioxide, sand
occupational standardSTEL 0.3 mg/m3
auto-ignition temperature899 °F


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