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2-Butene-1,4-Diol CAS No. 110-64-5

110-64-5 - Names and IdentifiersName2-Butene-1,4-diolSynonymsButenediolagrisynthb2dbutene-1,4-d

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110-64-5 - Names and Identifiers

Name2-Butene-1,4-diol
SynonymsButenediol
agrisynthb2d
butene-1,4-diol
2-Butene-1,4-diol
but-2-ene-1,4-diol
1,4-buenedilo(liquid)
1,4-Dihydroxy-2-butene
(2E)-2-Butene-1,4-diol
(Z)-but-2-ene-1,4-diol
(2Z)-but-2-ene-1,4-diol
(E)-but-2-ene-1,4-diol
(2E)-but-2-ene-1,4-diol
CIS-1,4-DIHYDROXY-2-BUTENE
CAS110-64-5
EINECS203-787-0
InChIInChI=1/2C4H8O2/c2*5-3-1-2-4-6/h2*1-2,5-6H,3-4H2/b2-1+;2-1-

110-64-5 - Physico-chemical Properties

Molecular FormulaC4H8O2
Molar Mass88.11
Density1.07 g/mL at 25 °C(lit.)
Melting Point4-10°C(lit.)
Boling Point235°C(lit.)
Flash Point>230°F
Water Solubility131.4 at 12 mm Hg
Vapor Presure2.46E-07mmHg at 25°C
Coloryellow
pKa14.17±0.10(Predicted)
Refractive Indexn20/D 1.479
Physical and Chemical PropertiesCharacter: colorless liquid.
boiling point 84 ℃
relative density 1.070
refractive index 1.4770
flash point 128 ℃
soluble in water, ethanol, acetone, almost insoluble in lower aliphatic hydrocarbons or aromatic hydrocarbons.
UseIt can be used as plasticizer of alkyd resin, crosslinking agent of synthetic resin, bactericide, etc. It can also be used for making nylon, Medicine, 1, 4-butanediol, etc

110-64-5 - Risk and Safety

Hazard SymbolsXn - Harmful

Risk CodesR22 - Harmful if swallowed
R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS23 - Do not breathe vapour.
S24/25 - Avoid contact with skin and eyes.
S36 - Wear suitable protective clothing.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany3
RTECSEM4970000
FLUKA BRAND F CODES23
HS Code29053990

110-64-5 - Upstream Downstream Industry

Raw MaterialsCalcium carbide
Formaldehyde
Downstream Productsendosulfan

110-64-5 - Reference Information

Applicationused as plasticizer of alkyd resin, crosslinking agent of synthetic resin, bactericide, etc,
1, 4-butenediol is a pesticide and pharmaceutical intermediate, which is used in the synthesis of organic chlorine pesticide endosulfan.
It is mainly used as an intermediate for preparing pesticides, agricultural chemicals and vitamin B6, and is used in a small amount for polymer production.
used as plasticizer for alkyd resin, cross-linking agent for synthetic resin, bactericide, etc., and also used for making nylon, Medicine, 1, 4-butanediol and so on
production methodis obtained by catalytic hydrogenation of butynediol. After mixing a 40% aqueous solution of butynediol with 50% of Raney nickel, ammonia water as a inhibitor was added, and hydrogen was applied at a pressure of about 0.5MPa until the theoretical hydrogen absorption amount was reached. After filtration, the filtrate was distilled under reduced pressure, and the 110-114 ° C. (8kPa) fraction was collected to obtain butenediol.
The preparation method is catalytic hydrogenation of 1, 4-butynediol to obtain 1, 4-butenediol. After mixing 40% aqueous butynediol solution with 50% Raney nickel, inhibitor ammonia water was added, and hydrogen gas was introduced at a pressure of about 0.5kPa until the theoretical hydrogen absorption amount was reached. After filtration, the filtrate was distilled under reduced pressure, and a fraction of 110 to 114 ° C./8kPa was collected to obtain 1, 4-butenediol.
categoryflammable liquid
toxicity gradepoisoning
Acute toxicityoral-rat LD50: 1250 mg/kg; Intraperitoneal-rat LD50: 327 mg/kg
flammability hazard characteristicsflammability; Combustion stimulus smoke
storage and transportation characteristicswarehouse ventilation and low temperature drying
extinguishing agentdry powder, foam, water

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